I created a Windows Application Project and Added reference of the following libraries

atk-sharp.dll
gdk-sharp.dll
glade-sharp.dll
glib-sharp.dll
gtk-dotnet.dll
gtk-sharp.dll

And I deleted the Form1. And modified the Program.cs; the Program.cs

namespace HelloGtk
{
    using System;
    using Gtk;

    public class Program
    {
        private MainWindow mainWindow = null;

        public Program()
        {
            Application.Init();
            mainWindow = new MainWindow();
            Application.Run();
        }

        static void Main()
        {
            new Program();
            return;
        }
    }
}

And the added a class MainWindow.cs, and wrote the code

namespace HelloGtk
{
    using Gtk;
    using System.IO;

    public class MainWindow : Gtk.Window
    {
        private string title = "Text File Viewer";
        private VBox vbox;
        private MenuBar menubar;
        private Statusbar statusbar;
        private TextView textView;
        private ScrolledWindow scrolledWindow;
        private AccelGroup accelGroup;
        private Toolbar toolbar;
        public MainWindow()
            : base("Text File Viewer")
        {
            this.DefaultSize = new Gdk.Size(600, 500);
            this.DeleteEvent += new DeleteEventHandler(MainWindow_DeleteEvent);
            this.Build();
        }

        private void MainWindow_DeleteEvent(object o, DeleteEventArgs args)
        {
            Application.Quit();
            args.RetVal = true;
        }

        private void Build()
        {
            this.Title = this.title;
            this.vbox = new VBox(false, 0);
            this.CreateMenubar();
            this.vbox.PackStart(this.menubar, false, true, 0);
            this.toolbar = new Toolbar();
            this.CreateToolbar();
            this.vbox.PackStart(this.toolbar, false, true, 0);
            this.textView = new TextView();
            this.textView.Editable = false;
            this.textView.WrapMode = WrapMode.Word;
            this.scrolledWindow = new ScrolledWindow();
            this.scrolledWindow.SetPolicy(PolicyType.Automatic, PolicyType.Automatic);
            this.scrolledWindow.Add(this.textView);
            this.vbox.PackStart(this.scrolledWindow, true, true, 0);
            this.statusbar = new Statusbar();
            this.vbox.PackStart(this.statusbar, false, true, 0);
            this.Add(this.vbox);
            this.ShowAll();
        }
        private void CreateToolbar()
        {
            ToolButton OpenToolBarBtn = new ToolButton("gtk-open");
            OpenToolBarBtn.Clicked += this.openMenu_Activated;
            SeparatorToolItem Sep1 = new SeparatorToolItem();
            ToolButton CopyToolBarBtn = new ToolButton("gtk-copy");
            CopyToolBarBtn.Clicked += this.copyMenu_Activated;
            SeparatorToolItem Sep2 = new SeparatorToolItem();
            ToolButton AboutToolBarBtn = new ToolButton("gtk-about");
            AboutToolBarBtn.Clicked += this.aboutMenu_Activated;

            this.toolbar.Add(OpenToolBarBtn);
            this.toolbar.Add(Sep1);
            this.toolbar.Add(CopyToolBarBtn);
            this.toolbar.Add(Sep2);
            this.toolbar.Add(AboutToolBarBtn);
        }

        private void CreateMenubar()
        {
            this.accelGroup = new AccelGroup();
            this.menubar = new MenuBar();
            MenuItem fileMenu = new MenuItem("_File");
            MenuItem editMenu = new MenuItem("_Edit");
            MenuItem helpMenu = new MenuItem("_Help");
            helpMenu.RightJustified = true;

            Menu fileSubMenu = new Menu();
            TearoffMenuItem fileMenuTearOff = new TearoffMenuItem();
            ImageMenuItem openMenu = new ImageMenuItem("gtk-open", accelGroup);
            openMenu.Activated += new System.EventHandler(openMenu_Activated);
            SeparatorMenuItem fileMenuSep = new SeparatorMenuItem();
            ImageMenuItem exitMenu = new ImageMenuItem("gtk-quit", accelGroup);
            exitMenu.Activated += new System.EventHandler(exitMenu_Activated);
            fileSubMenu.Add(fileMenuTearOff);
            fileSubMenu.Add(openMenu);
            fileSubMenu.Add(fileMenuSep);
            fileSubMenu.Add(exitMenu);
            fileMenu.Submenu = fileSubMenu;

            Menu editSubMenu = new Menu();
            ImageMenuItem copyMenu = new ImageMenuItem("gtk-copy", accelGroup);
            copyMenu.Activated += new System.EventHandler(copyMenu_Activated);
            TearoffMenuItem editMenuTearOff = new TearoffMenuItem();
            editSubMenu.Add(editMenuTearOff);
            editSubMenu.Add(copyMenu);
            editMenu.Submenu = editSubMenu;

            Menu helpSubMenu = new Menu();
            ImageMenuItem aboutMenu = new ImageMenuItem("gtk-about", accelGroup);
            TearoffMenuItem helpMenuTearOff = new TearoffMenuItem();
            helpSubMenu.Add(helpMenuTearOff);
            helpSubMenu.Add(aboutMenu);
            aboutMenu.Activated += new System.EventHandler(aboutMenu_Activated);
            helpMenu.Submenu = helpSubMenu;

            this.menubar.Add(fileMenu);
            this.menubar.Add(editMenu);
            this.menubar.Add(helpMenu);
        }

        void aboutMenu_Activated(object sender, System.EventArgs e)
        {
            using (Dialog dialog = new MessageDialog(this,
                                  DialogFlags.Modal | DialogFlags.DestroyWithParent,
                                  MessageType.Info,
                                  ButtonsType.Ok,
                                  "Text File Viewer - A simple text file viewer using gtk#\nDeveloped by Anuraj\nPowered by dotnetthoughts.net\n\nUnder GNU GPL v2."))
            {
                dialog.Title = "About";
                dialog.Run();
                dialog.Hide();
            }
        }

        private void copyMenu_Activated(object sender, System.EventArgs e)
        {
            Clipboard clipboad = this.textView.GetClipboard(Gdk.Selection.Clipboard);
            this.textView.Buffer.CopyClipboard(clipboad);
        }

        void exitMenu_Activated(object sender, System.EventArgs e)
        {
            Application.Quit();
        }
        FileChooserDialog dlg;
        private void openMenu_Activated(object sender, System.EventArgs e)
        {
            dlg =
                new FileChooserDialog("Select Text File", this, FileChooserAction.Open, "");
            dlg.AddButton("Open File", ResponseType.Ok);
            dlg.AddButton("Cancel", ResponseType.Cancel);

            FileFilter filter = new FileFilter();
            filter.AddPattern("*.txt");
            filter.AddPattern("*.*");
            dlg.Filter = filter;

            dlg.TypeHint = Gdk.WindowTypeHint.Dialog;
            dlg.SelectMultiple = false;
            dlg.WindowPosition = WindowPosition.Center;
            dlg.Parent = this;
            dlg.Modal = true;
            dlg.KeepAbove = true;
            dlg.DestroyWithParent = true;
            dlg.State = StateType.Normal;

            dlg.Response += new ResponseHandler(dlg_Response);
            dlg.DeleteEvent += new DeleteEventHandler(dlg_DeleteEvent);

            dlg.Run();
            dlg.Destroy();

        }

        private void dlg_DeleteEvent(object o, DeleteEventArgs args)
        {
            dlg.Destroy();
        }

        private void dlg_Response(object o, ResponseArgs args)
        {
            if (args.ResponseId == ResponseType.Ok)
            {
                this.Title = string.Format("{0} - {1}", this.title, System.IO.Path.GetFileName(dlg.Filename));
                using (StreamReader reader = new StreamReader(dlg.Filename, true))
                {
                    this.textView.Buffer.Text = reader.ReadToEnd();
                }
            }
            dlg.Destroy();
        }
    }
}

And run the application. Here is the screenshot, Text File Viewer running on my machine.

Text File Viewer using GTK#