I am attaching the code to export all the slides from a Power Point to Images

string ExportLocation = "C:\\Sample";
Microsoft.Office.Interop.PowerPoint.Application ppApp = new Microsoft.Office.Interop.PowerPoint.Application();
ppApp.Visible = MsoTriState.msoTrue;
ppApp.WindowState = PpWindowState.ppWindowMinimized;
Microsoft.Office.Interop.PowerPoint.Presentations oPresSet = ppApp.Presentations;
Microsoft.Office.Interop.PowerPoint._Presentation oPres = oPresSet.Open("C:\\ScreenShots.ppt",
            MsoTriState.msoFalse, MsoTriState.msoFalse,
            MsoTriState.msoFalse);
ppApp.ShowWindowsInTaskbar = MsoTriState.msoFalse;	//Hiding the application; But it will be displayed always
try
{
    Slides objSlides = oPres.Slides;	//Getting all the slides
    for (int i = 1; i < objSlides.Count - 1; i++)
    {
        string file = Path.Combine(ExportLocation, string.Format("{0}.{1}", objSlides[i].Name, "jpg"));
        oPres.Slides[i].Export(file, "jpg", 800, 600);
    }
}
finally
{
    ppApp.Quit();	//Closing the Powerpoint application. Sometimes it won't work too.
}

Thanks to ArunKumar, for providing the code snippet.

Here is the code to call word macros from VB.Net.

Dim WordApp As New Microsoft.Office.Interop.Word.Application
CType(WordApp, Object).GetType().InvokeMember("Run", Reflection.BindingFlags.Default Or Reflection.BindingFlags.InvokeMethod, Nothing, CType(WordApp, Object), New Object() {"helloworld"})

In the code, helloworld is the macro name.Or you can simply call WordApp.Run("helloworld") will also works fine.

You can also refer link from Microsoft
http://support.microsoft.com/kb/306683